Supplementary Cementitious Materials and Blended Cements
Most of the carbon footprint in concrete comes from cement. Reducing cement can be accomplished by using supplementary cementitious materials (SCMs) as a portion of the cementitious materials. SCMs can be separately batched when producing concrete or included when using a blended cement. To allow the most flexibility, permit all types of SCMs in concrete and do not place prescriptive limits on their use, unless required by the code applicable to the project (note that prescriptive SCM limits are only required in ACI 318 for certain circumstances, for example concrete subject to the application of deicing salts).
Some commonly used SCMs used in concrete are fly ash (ASTM 618 Class C and Class F), ground granulated blast furnace slag (slag cement, ASTM C989), or raw or calcined natural pozzolans (ASTM C618 Class N and ASTM C1945), blended SCMs (ASTM C1697), and other pozzolans including ground recycled glass (ASTM C1866). ASTM C1912 is a new performance specification to cover novel SCMs that do not meet other standard specifications and is employed in combination with ASTM C1709’s guide to evaluating alternative SCMs. Regional availability is a factor, checking with local material suppliers to determine what SCMs are available can help engineers plan more achievable low embodied carbon strategies.
Permit the use of blended hydraulic cements (ASTM C595) and hydraulic cement (ASTM C1157) in the specification. The different types of ASTM C595 cements include:
| Cement Type |
Cement Name |
Limestone |
Pozzolan |
Slag |
Total (Limestone, Pozzolan & Slag) |
| Type IL |
Portland-Limestone Cement |
>5% & ≤15% |
– |
– |
– |
| Type IP |
Portland-Pozzolan Cement |
≤15% (optional) |
>0% & ≤40% |
– |
– |
| Type IS |
Portland Slag Cement
(Note 2) |
≤15% (optional) |
– |
>0% & ≤95% |
– |
| Type IT |
Ternary Blended Cement |
≤15% (optional) |
≤40% |
Note 1 |
≤70% |
| Type IT (S≥70) |
Ternary Blended Cement
(Note 2) |
≤15%
(optional) |
Note 1 |
≥70% |
≤95% |
| Type IC |
Composite Cement |
≤30% (optional) |
Note 1 |
Note 1 |
≤70% |
Notes:
- No stated maximum, but must satisfy limit on total limestone, pozzolan & slag cement.
- In practice, Type IS>70 is not permitted for structural applications and has limited availability (applies to both Type IS>70 & Type IT S>70)
ASTM C595 cements with higher SCM contents (30%, or 40% for slag) have lower early-age strength requirements, reflecting the delay in strength development that may be expected.Type IL is generally available in all regions. The same quantity of SCMs can be used in concrete made with Type IL cement as with mixtures with portland cement. Types IP, IS, IT, and IC cements are also growing in availability, although the SCMs in these products vary regionally.
ASTM C1157 (performance hydraulic cements) also include blended cements containing SCMs, but without prescriptive limits on their composition. Blended cements with more ingredients or higher SCM contents than permitted under ASTM C595 can be sold as ASTM C1157 cements.
It may not be feasible to reduce the portland cement content in all concrete mixtures used on a project due to lower strengths, greater setting times, or other factors. Allow suppliers the flexibility to tailor the SCM quantities in concrete mixtures to address sustainability requirements while balancing availability, cost, and performance.
When permitting the use of newer cements and SCMs, communication with the entire project team is critical. A supplier cannot simply substitute one cement type for another in an otherwise unchanged mix without treating it as a new mix design for review and approval. Different cements have different chemistries and physical characteristics, that in combination with other mixture constituents, can affect setting, workability, and finishing characteristics. Material suppliers are often best positioned to manage the introduction of new cements and SCMs, drawing on their historical data and experience with similar mixtures. Engage suppliers early to determine whether a proposed mixture has an established performance history or requires additional validation. For mixtures developed specifically for the project or otherwise lacking sufficient prior testing, consider specifying pre-qualification testing and mockups. Testing and mockups should be coordinated with the builder, supplier, and design team to confirm that key performance criteria are met for the specific project and application.